4-oxalomesaconate hydratase
Pathways
gallate degradation (BRENDA)






EC Number
Reaction
Pathways
Reaction IDs
Stoichiometry Check
Missing Substrate
Missing Product
Commentary
Remark
(E)-3-carboxy-5-oxo-2-hex-2-enedioic acid + H2O = 2-hydroxy-4-oxobutane-1,2,4-tricarboxylate
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gallic acid + O2 = 2-pyrone-4,6-dicarboxylic acid + H2O
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natural substrates
protocatechuate 3,4-dioxygenase
gallic acid + O2 = 2-pyrone-4,6-dicarboxylic acid + H2O
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natural substrates
protocatechuate 4,5-dioxygenase
gallic acid + O2 = 2-pyrone-4,6-dicarboxylic acid + H2O
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natural substrates
0.0.0.0
spontaneous reaction
4-oxalomesaconate = 4-carboxy-2-hydroxyhexa-2,4-dienedioate
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natural substrates
gallate dioxygenase
3,4,5-trihydroxybenzoate + O2 = (1E)-4-oxobut-1-ene-1,2,4-tricarboxylate
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natural substrates
protocatechuate 4,5-dioxygenase
3,4,5-trihydroxybenzoate + O2 = (1E)-4-oxobut-1-ene-1,2,4-tricarboxylate
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natural substrates
4-oxalomesaconate tautomerase
(1E)-4-oxobut-1-ene-1,2,4-tricarboxylate = (1E,3E)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate
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natural substrates
gallate decarboxylase
3,4,5-trihydroxybenzoate = 1,2,3-trihydroxybenzene + CO2
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natural substrates
4-hydroxybenzoate decarboxylase
3,4,5-trihydroxybenzoate = 1,2,3-trihydroxybenzene + CO2
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natural substrates
phloroglucinol reductase
dihydrophloroglucinol + NADP+ = phloroglucinol + NADPH + H+
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natural substrates