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BRENDA KEGG MetaCyc

fumitremorgin biosynthesis (BRENDA)

:= BRENDA, := KEGG, := MetaCyc, := SABIO-RK
:= amino acid sequences := show the reaction diagram
EC Number
Reaction
Pathways
Reaction IDs
Stoichiometry Check
Missing Substrate
Missing Product
Commentary
Remark
tryprostatin B synthase
dimethylallyl diphosphate + brevianamide F = diphosphate + tryprostatin B
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natural substrates
fumitremorgin C synthase
tryprostatin A + [reduced NADPH-hemoprotein reductase] + O2 = fumitremorgin C + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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natural substrates, generic, protein
tryprostatin B 6-hydroxylase
tryprostatin B + [reduced NADPH-hemoprotein reductase] + O2 = 6-hydroxytryprostatin B + [oxidized NADPH-hemoprotein reductase] + H2O
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natural substrates, generic, protein
6-hydroxytryprostatin B O-methyltransferase
S-adenosyl-L-methionine + 6-hydroxytryprostatin B = S-adenosyl-L-homocysteine + tryprostatin A
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natural substrates
fumitremorgin C monooxygenase
fumitremorgin C + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 = 12alpha,13alpha-dihydroxyfumitremorgin C + 2 [oxidized NADPH-hemoprotein reductase] + 2 H2O
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natural substrates, generic, protein
12alpha,13alpha-dihydroxyfumitremorgin C prenyltransferase
dimethylallyl diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin C = diphosphate + fumitremorgin B
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natural substrates
verruculogen synthase
fumitremorgin B + 2-oxoglutarate + 2 O2 + reduced acceptor = verruculogen + succinate + CO2 + H2O + acceptor
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natural substrates, generic
verruculogen prenyltransferase
dimethylallyl diphosphate + verruculogen = diphosphate + fumitremorgin A
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natural substrates