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BRENDA KEGG MetaCyc

benzoxazinoid glucosides biosynthesis (BRENDA)

:= BRENDA, := KEGG, := MetaCyc, := SABIO-RK
:= amino acid sequences := show the reaction diagram
EC Number
Reaction
Pathways
Reaction IDs
Stoichiometry Check
Missing Substrate
Missing Product
Commentary
Remark
2,4,7-trihydroxy-1,4-benzoxazin-3-one-glucoside 7-O-methyltransferase
S-adenosyl-L-methionine + (2R)-4,7-dihydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside = S-adenosyl-L-homocysteine + (2R)-4-hydroxy-7-methoxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside
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: O-methyltransferase BX7
natural substrates
2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase
DIBOA-glucoside + 2-Oxoglutarate + Oxygen <=> TRIBOA-glucoside + Succinate + CO2
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: 2-oxoglutarate-dependent dioxygenase BX6
natural substrates
2,4-dihydroxy-7-methoxy-2H-1,4-benzoxazin-3(4H)-one 2-D-glucosyltransferase
UDP-alpha-D-glucose + 2,4-dihydroxy-2H-1,4-benzoxazin-3(4H)-one = UDP + (2R)-4-hydroxy-3-oxo-3,4-dihydro-2H-1,4-benzoxazin-2-yl beta-D-glucopyranoside
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: UDP-glucosyltransferase, bx8, bx9
natural substrates
2-hydroxy-1,4-benzoxazin-3-one monooxygenase
2-hydroxy-2H-1,4-benzoxazin-3(4H)-one + [reduced NADPH-hemoprotein reductase] + O2 = 2,4-dihydroxy-2H-1,4-benzoxazin-3(4H)-one + [oxidized NADPH-hemoprotein reductase] + H2O
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natural substrates, generic, protein
3-hydroxyindolin-2-one monooxygenase
3-hydroxyindolin-2-one + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2H-1,4-benzoxazin-3(4H)-one + [oxidized NADPH-hemoprotein reductase] + H2O
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natural substrates, generic, protein
indolin-2-one monooxygenase
indolin-2-one + [reduced NADPH-hemoprotein reductase] + O2 = 3-hydroxyindolin-2-one + [oxidized NADPH-hemoprotein reductase] + H2O
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: Cytochrome P450 monooxygenase (CYP71C2), bx3
natural substrates, generic, protein
indole-2-monooxygenase
indole + [reduced NADPH-hemoprotein reductase] + O2 = indolin-2-one + [oxidized NADPH-hemoprotein reductase] + H2O
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natural substrates, generic, protein
indole-3-glycerol-phosphate lyase
(1S,2R)-1-C-(indol-3-yl)glycerol 3-phosphate = indole + D-glyceraldehyde 3-phosphate
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: a part of multi-step reaction (ec 4.2.1.20, see R02722, R02340+R00674)
natural substrates
tryptophan synthase
(1S,2R)-1-C-(indol-3-yl)glycerol 3-phosphate = indole + D-glyceraldehyde 3-phosphate
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: a part of multi-step reaction (ec 4.2.1.20, see R02722, R02340+R00674)
natural substrates