Pathways

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BRENDA KEGG MetaCyc

aerobic toluene degradation (BRENDA)
:= BRENDA, := KEGG, := MetaCyc, := SABIO-RK
:= amino acid sequences := show the reaction diagram
EC Number
Reaction
Pathways
Reaction IDs
Stoichiometry Check
Missing Substrate
Missing Product
Commentary
Remark
3-oxoadipate CoA-transferase
succinyl-CoA + 3-oxoadipate = succinate + 3-oxoadipyl-CoA
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments
: 3-oxoadipate degradation
: BR48131show the reaction diagram
: R02990show the reaction diagram
: 3-OXOADIPATE-COA-TRANSFERASE-RXNshow the reaction diagram
: 2842
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-
-
natural substrates
4-carboxymuconolactone decarboxylase
(R)-2-carboxy-2,5-dihydro-5-oxofuran-2-acetate = 4,5-dihydro-5-oxofuran-2-acetate + CO2
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: protocatechuate degradation II (ortho-cleavage pathway)
: BR3361show the reaction diagram, BS18492show the reaction diagram
: R03470show the reaction diagram
: 4-CARBOXYMUCONOLACTONE-DECARBOXYLASE-RXNshow the reaction diagram
-
-
-
-
natural substrates
3-carboxy-cis,cis-muconate cycloisomerase
cis,cis-butadiene-1,2,4-tricarboxylate = 2-carboxy-2,5-dihydro-5-oxofuran-2-acetate
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: protocatechuate degradation II (ortho-cleavage pathway)
: BR260show the reaction diagram, BR263show the reaction diagram
: R03307show the reaction diagram, R03308show the reaction diagram
: 5.5.1.2-RXNshow the reaction diagram, CARBOXY-CISCIS-MUCONATE-CYCLASE-RXNshow the reaction diagram
: 3123
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-
natural substrates
Carboxy-cis,cis-muconate cyclase
cis,cis-butadiene-1,2,4-tricarboxylate = 2-carboxy-2,5-dihydro-5-oxofuran-2-acetate
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: protocatechuate degradation II (ortho-cleavage pathway)
: BR260show the reaction diagram, BR263show the reaction diagram
: R03307show the reaction diagram, R03308show the reaction diagram
: 5.5.1.2-RXNshow the reaction diagram, CARBOXY-CISCIS-MUCONATE-CYCLASE-RXNshow the reaction diagram
: 3123
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-
-
-
natural substrates
protocatechuate 3,4-dioxygenase
3,4-dihydroxybenzoate + O2 = 3-carboxy-cis,cis-muconate
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Polycyclic aromatic hydrocarbon degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: protocatechuate degradation II (ortho-cleavage pathway)
: BR40477show the reaction diagram
: R01631show the reaction diagram
: PROTOCATECHUATE-34-DIOXYGENASE-RXNshow the reaction diagram
-
-
-
-
natural substrates
4-hydroxybenzoate 3-monooxygenase
4-hydroxybenzoate + NADPH + H+ + O2 = 3,4-dihydroxybenzoate + NADP+ + H2O
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 4-coumarate degradation (aerobic),
polybrominated dihydroxylated diphenyl ethers biosynthesis,
spongiadioxin C biosynthesis,
bisphenol A degradation,
4-methylphenol degradation to protocatechuate,
4-chlorobenzoate degradation,
4-hydroxymandelate degradation
: BR36759show the reaction diagram
: R01298show the reaction diagram
: 1.14.13.33-RXNshow the reaction diagram, 4-HYDROXYBENZOATE-3-MONOOXYGENASE-RXNshow the reaction diagram
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-
: NADH (ec 1.14.13.33, see R1296)
natural substrates
4-hydroxybenzoate 3-monooxygenase [NAD(P)H]
4-hydroxybenzoate + NADPH + H+ + O2 = 3,4-dihydroxybenzoate + NADP+ + H2O
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 4-coumarate degradation (aerobic),
polybrominated dihydroxylated diphenyl ethers biosynthesis,
spongiadioxin C biosynthesis,
bisphenol A degradation,
4-methylphenol degradation to protocatechuate,
4-chlorobenzoate degradation,
4-hydroxymandelate degradation
: BR36759show the reaction diagram
: R01298show the reaction diagram
: 1.14.13.33-RXNshow the reaction diagram, 4-HYDROXYBENZOATE-3-MONOOXYGENASE-RXNshow the reaction diagram
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: NADH (ec 1.14.13.33, see R1296)
natural substrates
aldehyde dehydrogenase (NADP+)
4-hydroxybenzaldehyde + NADP+ + H2O = 4-hydroxybenzoate + NADPH + 2 H+
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Toluene degradation,
Aminobenzoate degradation,
Microbial metabolism in diverse environments
: 4-methylphenol degradation to protocatechuate,
4-hydroxymandelate degradation,
4-coumarate degradation (aerobic),
4-coumarate degradation (anaerobic)
: BR51337show the reaction diagram
: R01294show the reaction diagram
: HYDROXYBENZALDEHYDE-OXIDATION-NADP-RXNshow the reaction diagram, RXN-13394show the reaction diagram
: 1509
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natural substrates
aldehyde dehydrogenase [NAD(P)+]
4-hydroxybenzaldehyde + NADP+ + H2O = 4-hydroxybenzoate + NADPH + 2 H+
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Toluene degradation,
Aminobenzoate degradation,
Microbial metabolism in diverse environments
: 4-methylphenol degradation to protocatechuate,
4-hydroxymandelate degradation,
4-coumarate degradation (aerobic),
4-coumarate degradation (anaerobic)
: BR51337show the reaction diagram
: R01294show the reaction diagram
: HYDROXYBENZALDEHYDE-OXIDATION-NADP-RXNshow the reaction diagram, RXN-13394show the reaction diagram
: 1509
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-
natural substrates
vanillin dehydrogenase
4-hydroxybenzaldehyde + NADP+ + H2O = 4-hydroxybenzoate + NADPH + 2 H+
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Toluene degradation,
Aminobenzoate degradation,
Microbial metabolism in diverse environments
: 4-methylphenol degradation to protocatechuate,
4-hydroxymandelate degradation,
4-coumarate degradation (aerobic),
4-coumarate degradation (anaerobic)
: BR51337show the reaction diagram
: R01294show the reaction diagram
: HYDROXYBENZALDEHYDE-OXIDATION-NADP-RXNshow the reaction diagram, RXN-13394show the reaction diagram
: 1509
-
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-
natural substrates
benzaldehyde dehydrogenase (NADP+)
4-hydroxybenzaldehyde + NADP+ + H2O = 4-hydroxybenzoate + NADPH + 2 H+
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Toluene degradation,
Aminobenzoate degradation,
Microbial metabolism in diverse environments
: 4-methylphenol degradation to protocatechuate,
4-hydroxymandelate degradation,
4-coumarate degradation (aerobic),
4-coumarate degradation (anaerobic)
: BR51337show the reaction diagram
: R01294show the reaction diagram
: HYDROXYBENZALDEHYDE-OXIDATION-NADP-RXNshow the reaction diagram, RXN-13394show the reaction diagram
: 1509
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-
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-
natural substrates
4-hydroxybenzaldehyde dehydrogenase (NADP+)
4-hydroxybenzaldehyde + NADP+ + H2O = 4-hydroxybenzoate + NADPH + 2 H+
: aerobic toluene degradation,
4-hydroxymandelate degradation
: Toluene degradation,
Aminobenzoate degradation,
Microbial metabolism in diverse environments
: 4-methylphenol degradation to protocatechuate,
4-hydroxymandelate degradation,
4-coumarate degradation (aerobic),
4-coumarate degradation (anaerobic)
: BR51337show the reaction diagram
: R01294show the reaction diagram
: HYDROXYBENZALDEHYDE-OXIDATION-NADP-RXNshow the reaction diagram, RXN-13394show the reaction diagram
: 1509
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-
natural substrates
4-methylphenol dehydrogenase (hydroxylating)
4-hydroxybenzyl alcohol + 2 oxidized azurin = 4-hydroxybenzaldehyde + 2 reduced azurin + 2 H+
: aerobic toluene degradation
: 4-methylphenol degradation to protocatechuate
: BR52448show the reaction diagram
: R12134show the reaction diagram
: RXN-16205show the reaction diagram
generic compounds
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: the second step of two-step reaction (see R02675, R12133+R12134)
natural substrates, generic
4-hydroxybenzyl alcohol + 2 oxidized azurin = 4-hydroxybenzaldehyde + 2 reduced azurin + 2 H+
: aerobic toluene degradation
: 4-methylphenol degradation to protocatechuate
: BR52448show the reaction diagram
: R12134show the reaction diagram
: RXN-16205show the reaction diagram
generic compounds
-
-
: the second step of two-step reaction (see R02675, R12133+R12134)
natural substrates, generic
acetaldehyde dehydrogenase (acetylating)
acetaldehyde + CoA + NAD+ = acetyl-CoA + NADH + H+
: aerobic toluene degradation,
3-phenylpropionate degradation,
threonine metabolism,
ethanol fermentation
: Phenylalanine metabolism,
Benzoate degradation,
Pyruvate metabolism,
Dioxin degradation,
Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2-hydroxypenta-2,4-dienoate degradation,
sulfoacetaldehyde degradation IV,
2-deoxy-D-ribose degradation I,
L-threonine degradation IV,
ethanolamine utilization,
heterolactic fermentation,
triethylamine degradation,
2-deoxy-alpha-D-ribose 1-phosphate degradation,
superpathway of fermentation (Chlamydomonas reinhardtii),
pyruvate fermentation to ethanol III,
mixed acid fermentation,
acetylene degradation (anaerobic),
pyruvate fermentation to ethanol I,
2-aminoethylphosphonate degradation I,
ethanol degradation I
: BR36771show the reaction diagram
: R00228show the reaction diagram
: ACETALD-DEHYDROG-RXNshow the reaction diagram
: 163
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natural substrates
hexadecanal dehydrogenase (acylating)
acetaldehyde + CoA + NAD+ = acetyl-CoA + NADH + H+
: aerobic toluene degradation,
3-phenylpropionate degradation,
threonine metabolism,
ethanol fermentation
: Phenylalanine metabolism,
Benzoate degradation,
Pyruvate metabolism,
Dioxin degradation,
Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2-hydroxypenta-2,4-dienoate degradation,
sulfoacetaldehyde degradation IV,
2-deoxy-D-ribose degradation I,
L-threonine degradation IV,
ethanolamine utilization,
heterolactic fermentation,
triethylamine degradation,
2-deoxy-alpha-D-ribose 1-phosphate degradation,
superpathway of fermentation (Chlamydomonas reinhardtii),
pyruvate fermentation to ethanol III,
mixed acid fermentation,
acetylene degradation (anaerobic),
pyruvate fermentation to ethanol I,
2-aminoethylphosphonate degradation I,
ethanol degradation I
: BR36771show the reaction diagram
: R00228show the reaction diagram
: ACETALD-DEHYDROG-RXNshow the reaction diagram
: 163
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natural substrates
butanal dehydrogenase
acetaldehyde + CoA + NAD+ = acetyl-CoA + NADH + H+
: aerobic toluene degradation,
3-phenylpropionate degradation,
threonine metabolism,
ethanol fermentation
: Phenylalanine metabolism,
Benzoate degradation,
Pyruvate metabolism,
Dioxin degradation,
Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2-hydroxypenta-2,4-dienoate degradation,
sulfoacetaldehyde degradation IV,
2-deoxy-D-ribose degradation I,
L-threonine degradation IV,
ethanolamine utilization,
heterolactic fermentation,
triethylamine degradation,
2-deoxy-alpha-D-ribose 1-phosphate degradation,
superpathway of fermentation (Chlamydomonas reinhardtii),
pyruvate fermentation to ethanol III,
mixed acid fermentation,
acetylene degradation (anaerobic),
pyruvate fermentation to ethanol I,
2-aminoethylphosphonate degradation I,
ethanol degradation I
: BR36771show the reaction diagram
: R00228show the reaction diagram
: ACETALD-DEHYDROG-RXNshow the reaction diagram
: 163
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natural substrates
propanal dehydrogenase (CoA-propanoylating)
acetaldehyde + CoA + NAD+ = acetyl-CoA + NADH + H+
: aerobic toluene degradation,
3-phenylpropionate degradation,
threonine metabolism,
ethanol fermentation
: Phenylalanine metabolism,
Benzoate degradation,
Pyruvate metabolism,
Dioxin degradation,
Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2-hydroxypenta-2,4-dienoate degradation,
sulfoacetaldehyde degradation IV,
2-deoxy-D-ribose degradation I,
L-threonine degradation IV,
ethanolamine utilization,
heterolactic fermentation,
triethylamine degradation,
2-deoxy-alpha-D-ribose 1-phosphate degradation,
superpathway of fermentation (Chlamydomonas reinhardtii),
pyruvate fermentation to ethanol III,
mixed acid fermentation,
acetylene degradation (anaerobic),
pyruvate fermentation to ethanol I,
2-aminoethylphosphonate degradation I,
ethanol degradation I
: BR36771show the reaction diagram
: R00228show the reaction diagram
: ACETALD-DEHYDROG-RXNshow the reaction diagram
: 163
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natural substrates
4-hydroxy-2-oxovalerate aldolase
(S)-4-hydroxy-2-oxopentanoate = acetaldehyde + pyruvate
: aerobic toluene degradation
: 2-hydroxypenta-2,4-dienoate degradation
: BR48692show the reaction diagram
: MHPELY-RXNshow the reaction diagram
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natural substrates
4-hydroxy-2-oxohexanoate aldolase
(S)-4-hydroxy-2-oxopentanoate = acetaldehyde + pyruvate
: aerobic toluene degradation
: 2-hydroxypenta-2,4-dienoate degradation
: BR48692show the reaction diagram
: MHPELY-RXNshow the reaction diagram
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natural substrates
2-oxopent-4-enoate hydratase
(S)-4-hydroxy-2-oxopentanoate = (2Z)-2-hydroxypenta-2,4-dienoate + H2O
: aerobic toluene degradation,
3-phenylpropionate degradation,
phenol degradation
: 2-hydroxypenta-2,4-dienoate degradation
: BR48326show the reaction diagram
: 2-OXOPENT-4-ENOATE-HYDRATASE-RXNshow the reaction diagram
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natural substrates
2-oxopent-4-enoate hydratase
4-hydroxy-2-oxopentanoate = 2-oxopent-4-enoate + H2O
: aerobic toluene degradation
: Phenylalanine metabolism,
Benzoate degradation,
Dioxin degradation,
Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: BS363305show the reaction diagram, BS378380show the reaction diagram
: R02601show the reaction diagram
: 2507
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natural substrates
2-hydroxymuconate-6-semialdehyde hydrolase
2-hydroxymuconate-6-semialdehyde + H2O = formate + 2-oxopent-4-enoate
: aerobic toluene degradation,
phenol degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: BR26140show the reaction diagram
: R02604show the reaction diagram
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natural substrates
2-oxo-3-hexenedioate decarboxylase
(3E)-2-oxohex-3-enedioate = 2-oxopent-4-enoate + CO2
: aerobic toluene degradation,
phenol degradation
: BR338show the reaction diagram
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natural substrates
2-hydroxymuconate tautomerase
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate = (3E)-2-oxohex-3-enedioate
: aerobic toluene degradation,
phenol degradation
: Benzoate degradation,
Dioxin degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: orthanilate degradation,
2,2'-dihydroxybiphenyl degradation,
2,3-dihydroxybenzoate degradation,
4-amino-3-hydroxybenzoate degradation,
catechol degradation to 2-hydroxypentadienoate II,
protocatechuate degradation III (para-cleavage pathway),
3-chlorocatechol degradation III (meta pathway)
: BR50210show the reaction diagram, BS419260show the reaction diagram, BS419261show the reaction diagram, BS419897show the reaction diagram
: R03966show the reaction diagram
: RXN-12354show the reaction diagram, RXN-8529show the reaction diagram
: 3703
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: CPD-13339 spontaneously converts to CPD-8742 in an aqueous solution, but the process is slow (about a 7-min half-life under the experimental conditions) [9573204].
natural substrates
5.3.2.M1
(2Z,4E)-2-hydroxyhexa-2,4-dienedioate = (3E)-2-oxohex-3-enedioate
: aerobic toluene degradation,
phenol degradation
: Benzoate degradation,
Dioxin degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: orthanilate degradation,
2,2'-dihydroxybiphenyl degradation,
2,3-dihydroxybenzoate degradation,
4-amino-3-hydroxybenzoate degradation,
catechol degradation to 2-hydroxypentadienoate II,
protocatechuate degradation III (para-cleavage pathway),
3-chlorocatechol degradation III (meta pathway)
: BR50210show the reaction diagram, BS419260show the reaction diagram, BS419261show the reaction diagram, BS419897show the reaction diagram
: R03966show the reaction diagram
: RXN-12354show the reaction diagram, RXN-8529show the reaction diagram
: 3703
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: CPD-13339 spontaneously converts to CPD-8742 in an aqueous solution, but the process is slow (about a 7-min half-life under the experimental conditions) [9573204].
natural substrates
toluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+ = benzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to benzoate
: BR52308show the reaction diagram
: R02550show the reaction diagram
: TOLUENE-SIDE-CHAIN-MONOOXYGENASE-RXNshow the reaction diagram
generic compounds
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: Oxidized ferredoxin is re-reduced by NADH (see R05875)
natural substrates, generic, protein
toluene methyl-monooxygenase
toluene + O2 + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+ = benzyl alcohol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to benzoate
: BR52308show the reaction diagram
: R02550show the reaction diagram
: TOLUENE-SIDE-CHAIN-MONOOXYGENASE-RXNshow the reaction diagram
generic compounds
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: Oxidized ferredoxin is re-reduced by NADH (see R05875)
natural substrates, generic, protein
aminobutyraldehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
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-
: general reaction
natural substrates
succinate-semialdehyde dehydrogenase (NAD+)
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
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-
: general reaction
natural substrates
benzaldehyde dehydrogenase (NAD+)
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
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-
: general reaction
natural substrates
aryl-aldehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
aldehyde dehydrogenase (NAD+)
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
L-aminoadipate-semialdehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
retinal dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
long-chain-aldehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
aldehyde dehydrogenase [NAD(P)+]
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
4-hydroxybenzaldehyde dehydrogenase (NAD+)
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
salicylaldehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
vanillin dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
fluoroacetaldehyde dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
aldehyde ferredoxin oxidoreductase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
alcohol dehydrogenase
an aromatic aldehyde + NAD+ + H2O = an aromatic acid + NADH + H+
: aerobic toluene degradation
: Toluene degradation,
Aminobenzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: D-phenylglycine degradation,
salicortin biosynthesis,
salicin biosynthesis,
benzoate biosynthesis III (CoA-dependent, non-beta-oxidative),
benzoate biosynthesis II (CoA-independent, non-beta-oxidative),
toluene degradation to benzoate,
mandelate degradation I
: BR29397show the reaction diagram, BR36777show the reaction diagram
: R01419show the reaction diagram, R01486show the reaction diagram
: ARYL-ALDEHYDE-DEHYDROGENASE-RXNshow the reaction diagram, BENZALDEHYDE-DEHYDROGENASE-NAD+-RXNshow the reaction diagram
: 1606
-
-
-
: general reaction
natural substrates
benzoate 1,2-dioxygenase
benzoate + NADH + H+ + O2 = (1R,6S)-1,6-dihydroxycyclohexa-2,4-diene-1-carboxylate + NAD+
: aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: benzoate degradation I (aerobic)
: BR37112show the reaction diagram, BS260922show the reaction diagram, BS398823show the reaction diagram
: R05621show the reaction diagram, R07188show the reaction diagram
: BENZOATE-12-DIOXYGENASE-RXNshow the reaction diagram
-
-
-
: BenA,BenB,BenC
natural substrates
1,6-dihydroxycyclohexa-2,4-diene-1-carboxylate dehydrogenase
(1R,6S)-1,6-dihydroxycyclohexa-2,4-diene-1-carboxylate + NAD+ = catechol + CO2 + NADH + H+
: aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: benzoate degradation I (aerobic)
: BR48039show the reaction diagram, BS359444show the reaction diagram
: R00813show the reaction diagram
: 1.3.1.25-RXNshow the reaction diagram
-
-
-
: BenD
natural substrates
3-carboxyethylcatechol 2,3-dioxygenase
catechol + O2 = 2-hydroxymuconate-6-semialdehyde
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: catechol degradation to 2-hydroxypentadienoate II,
catechol degradation to 2-hydroxypentadienoate I
: BR40485show the reaction diagram
: R00816show the reaction diagram
: CATECHOL-23-DIOXYGENASE-RXNshow the reaction diagram
: 1159
-
-
-
-
natural substrates
catechol 2,3-dioxygenase
catechol + O2 = 2-hydroxymuconate-6-semialdehyde
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: catechol degradation to 2-hydroxypentadienoate II,
catechol degradation to 2-hydroxypentadienoate I
: BR40485show the reaction diagram
: R00816show the reaction diagram
: CATECHOL-23-DIOXYGENASE-RXNshow the reaction diagram
: 1159
-
-
-
-
natural substrates
chloridazon-catechol dioxygenase
catechol + O2 = 2-hydroxymuconate-6-semialdehyde
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: catechol degradation to 2-hydroxypentadienoate II,
catechol degradation to 2-hydroxypentadienoate I
: BR40485show the reaction diagram
: R00816show the reaction diagram
: CATECHOL-23-DIOXYGENASE-RXNshow the reaction diagram
: 1159
-
-
-
-
natural substrates
hydroxyquinol 1,2-dioxygenase
catechol + O2 = 2-hydroxymuconate-6-semialdehyde
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: catechol degradation to 2-hydroxypentadienoate II,
catechol degradation to 2-hydroxypentadienoate I
: BR40485show the reaction diagram
: R00816show the reaction diagram
: CATECHOL-23-DIOXYGENASE-RXNshow the reaction diagram
: 1159
-
-
-
-
natural substrates
biphenyl-2,3-diol 1,2-dioxygenase
catechol + O2 = 2-hydroxymuconate-6-semialdehyde
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: catechol degradation to 2-hydroxypentadienoate II,
catechol degradation to 2-hydroxypentadienoate I
: BR40485show the reaction diagram
: R00816show the reaction diagram
: CATECHOL-23-DIOXYGENASE-RXNshow the reaction diagram
: 1159
-
-
-
-
natural substrates
aminomuconate-semialdehyde dehydrogenase
2-hydroxymuconate-6-semialdehyde + NAD+ + H2O = (2Z,4E)-2-hydroxyhexa-2,4-dienedioate + NADH + 2 H+
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2,3-dihydroxybenzoate degradation,
4-amino-3-hydroxybenzoate degradation,
catechol degradation to 2-hydroxypentadienoate II,
protocatechuate degradation III (para-cleavage pathway)
: BR50236show the reaction diagram, BS258087show the reaction diagram, BS370776show the reaction diagram
: R02762show the reaction diagram
: RXN-8527show the reaction diagram
-
-
-
-
natural substrates
2-hydroxymuconate-6-semialdehyde dehydrogenase
2-hydroxymuconate-6-semialdehyde + NAD+ + H2O = (2Z,4E)-2-hydroxyhexa-2,4-dienedioate + NADH + 2 H+
: phenol degradation,
aerobic toluene degradation
: Benzoate degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: 2,3-dihydroxybenzoate degradation,
4-amino-3-hydroxybenzoate degradation,
catechol degradation to 2-hydroxypentadienoate II,
protocatechuate degradation III (para-cleavage pathway)
: BR50236show the reaction diagram, BS258087show the reaction diagram, BS370776show the reaction diagram
: R02762show the reaction diagram
: RXN-8527show the reaction diagram
-
-
-
-
natural substrates
toluene 2-monooxygenase
toluene + NADH + H+ + O2 = 2-methylphenol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52669show the reaction diagram
: R03560show the reaction diagram
: TOLUENE-2-MONOOXYGENASE-RXNshow the reaction diagram
-
-
-
-
natural substrates
toluene 4-monooxygenase
2-methylphenol + NADH + H+ + O2 = 3-methylcatechol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52670show the reaction diagram
: R03608show the reaction diagram
: O-CRESOL-METHYLCATECHOL-RXNshow the reaction diagram
-
-
-
-
natural substrates
toluene 2-monooxygenase
2-methylphenol + NADH + H+ + O2 = 3-methylcatechol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52670show the reaction diagram
: R03608show the reaction diagram
: O-CRESOL-METHYLCATECHOL-RXNshow the reaction diagram
-
-
-
-
natural substrates
2-hydroxybiphenyl 3-monooxygenase
2-methylphenol + NADH + H+ + O2 = 3-methylcatechol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52670show the reaction diagram
: R03608show the reaction diagram
: O-CRESOL-METHYLCATECHOL-RXNshow the reaction diagram
-
-
-
-
natural substrates
phenol 2-monooxygenase (NADPH)
2-methylphenol + NADH + H+ + O2 = 3-methylcatechol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52670show the reaction diagram
: R03608show the reaction diagram
: O-CRESOL-METHYLCATECHOL-RXNshow the reaction diagram
-
-
-
-
natural substrates
toluene dioxygenase
toluene + NADH + H+ + O2 = (1S,2R)-3-methylcyclohexa-3,5-diene-1,2-diol + NAD+
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol)
: BR40532show the reaction diagram
: R03559show the reaction diagram
: TOLUENE-DIOXYGENASE-RXNshow the reaction diagram
-
-
-
-
natural substrates
3-methylcatechol + O2 = 2-hydroxy-6-oxohepta-2,4-dienoate
: aerobic toluene degradation
: Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BS260802show the reaction diagram, BS422529show the reaction diagram
: R04089show the reaction diagram
: CATECHOL-2-3-DIOXYGENASE-RXNshow the reaction diagram
: 3817
-
-
-
-
natural substrates
3-carboxyethylcatechol 2,3-dioxygenase
3-methylcatechol + O2 = 2-hydroxy-6-oxohepta-2,4-dienoate
: aerobic toluene degradation
: Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BS260802show the reaction diagram, BS422529show the reaction diagram
: R04089show the reaction diagram
: CATECHOL-2-3-DIOXYGENASE-RXNshow the reaction diagram
: 3817
-
-
-
-
natural substrates
catechol 2,3-dioxygenase
3-methylcatechol + O2 = 2-hydroxy-6-oxohepta-2,4-dienoate
: aerobic toluene degradation
: Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BS260802show the reaction diagram, BS422529show the reaction diagram
: R04089show the reaction diagram
: CATECHOL-2-3-DIOXYGENASE-RXNshow the reaction diagram
: 3817
-
-
-
-
natural substrates
biphenyl-2,3-diol 1,2-dioxygenase
3-methylcatechol + O2 = 2-hydroxy-6-oxohepta-2,4-dienoate
: aerobic toluene degradation
: Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BS260802show the reaction diagram, BS422529show the reaction diagram
: R04089show the reaction diagram
: CATECHOL-2-3-DIOXYGENASE-RXNshow the reaction diagram
: 3817
-
-
-
-
natural substrates
1,2-dihydroxynaphthalene dioxygenase
3-methylcatechol + O2 = 2-hydroxy-6-oxohepta-2,4-dienoate
: aerobic toluene degradation
: Xylene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BS260802show the reaction diagram, BS422529show the reaction diagram
: R04089show the reaction diagram
: CATECHOL-2-3-DIOXYGENASE-RXNshow the reaction diagram
: 3817
-
-
-
-
natural substrates
2-hydroxy-6-oxohepta-2,4-dienoate hydrolase
(2Z,4E)-2-hydroxy-6-oxohepta-2,4-dienoate + H2O = (2Z)-2-hydroxypenta-2,4-dienoate + acetate
: aerobic toluene degradation
: toluene degradation to 2-hydroxypentadienoate (via toluene-cis-diol),
2-nitrotoluene degradation,
toluene degradation to 2-hydroxypentadienoate I (via o-cresol)
: BR52750show the reaction diagram
: 2-OH-6-OXOHEPTA-2-4-DIENOATE-HYDR-RXNshow the reaction diagram
-
-
-
-
natural substrates
toluene 4-monooxygenase
toluene + NADH + H+ + O2 = 4-methylphenol + NAD+ + H2O
: aerobic toluene degradation
: Toluene degradation,
Metabolic pathways,
Microbial metabolism in diverse environments,
Degradation of aromatic compounds
: toluene degradation II (aerobic) (via 4-methylcatechol),
toluene degradation to 4-methylphenol
: BR52031show the reaction diagram
: R05666show the reaction diagram
: TOLUENE-4-MONOOXYGENASE-RXNshow the reaction diagram
-
-
-
-
natural substrates
4-methylphenol + 2 oxidized azurin + H2O = 4-hydroxybenzyl alcohol + 2 reduced azurin + 2 H+
: aerobic toluene degradation
: 4-methylphenol degradation to protocatechuate
: BR52447show the reaction diagram
: R12133show the reaction diagram
: RXN-16204show the reaction diagram
generic compounds
-
-
: the first step of two-step reaction (see R02675, R12133+R12134)
natural substrates, generic
4-methylphenol dehydrogenase (hydroxylating)
4-methylphenol + 2 oxidized azurin + H2O = 4-hydroxybenzyl alcohol + 2 reduced azurin + 2 H+
: aerobic toluene degradation
: 4-methylphenol degradation to protocatechuate
: BR52447show the reaction diagram
: R12133show the reaction diagram
: RXN-16204show the reaction diagram
generic compounds
-
-
: the first step of two-step reaction (see R02675, R12133+R12134)
natural substrates, generic